Liquid balance - steam for methanol mixing - Benzen using the Peng Robinson and Van-Laar models

Balance de líquidos - vapor para mezcla de metanol - benzen usando los modelos Peng Robinson y Van- Laar

Main Article Content

Miguel Fernando Palencia Muñoz
Natalia Prieto-Jiménez
Germán González Silva
Abstract

This paper is related to the procedure for calculating curves dew point and bubble point of a binary system, consisting of the methanol and benzene mixture to 45°C, using the Peng-Robinson cubic equation to calculate the fugacity coefficient of gas i in the mixture, and Van Laar model to calculate the activity coefficient of component i in the liquid mixture. Then a comparison between the theoretical data with the experimental data and later with the commercial simulator Hysys-Aspen, which applies the model of Wilson. The simulation was validated with experimental data,in addition to comparing the results with a commercial simulator.

Keywords

Downloads

Download data is not yet available.

Article Details

References

N. Prieto Jiménez y G. González Silva, «Comparative Study of Equations of State for the Dew Curves Calculation in High Pressure Natural Gas Mixtures.», Rev. Logos Cienc. Tecnol., vol. 11, n.o 1, p. 13, 2018.

J.-H. Oh, K.-J. Han, D.-B. Won, y S.-J. Park, «Vapor–liquid equilibria for the ternary systems of methyl tert-butyl ether+ methanol+ benzene and methyl tert-butyl ether+ methanol+ toluene and constituent binary systems at 313.15 K», Fluid Phase Equilibria, vol. 209, n.o 2, pp. 215-228, 2003.

J.-H. Oh y S.-J. Park, «Vapor− liquid equilibria for the ternary systems of methyl tert-butyl ether+ methanol+ methylcyclohexane and methyl tert-butyl ether+ methanol+ n-heptane and constituent binary systems at 313.15 K», J. Chem. Eng. Data, vol. 50, n.o 5, pp. 1564-1569, 2005.

M. K. Balki y C. Sayin, «The effect of compression ratio on the performance, emissions and combustion of an SI (spark ignition) engine fueled with pure ethanol, methanol and unleaded gasoline», Energy, vol. 71, pp. 194–201, 2014.

L. Wen, C.-Y. Xin, y S.-C. Yang, «The effect of adding dimethyl carbonate (DMC) and ethanol to unleaded gasoline on exhaust emission», Appl. Energy, vol. 87, n.o 1, pp. 115–121, 2010.

M. Eyidogan, A. N. Ozsezen, M. Canakci, y A. Turkcan, «Impact of alcohol–gasoline fuel blends on the performance and combustion characteristics of an SI engine», Fuel, vol. 89,n.o 10, pp. 2713–2720, 2010.

P. Iodice, G. Langella, y A. Amoresano, «Ethanol in gasoline fuel blends: Effect on fuel consumption and engine out emissions of SI engines in cold operating conditions»,Appl. Therm. Eng., vol. 130, pp. 1081-1089, 2018.

M. B. Gramajo y A. M. Cases, «Liquid–Liquid Equilibria of the Methanol+ Hexane+ Methylcyclohexane+ Toluene Quaternary System at T= 303.15 K», J. Solut. Chem., vol. 44,n.o 2, pp. 171-180, 2015.

B. E. García-Flores, J. Águila-Hernández, F. García-Sánchez, y M. A. Aquino-Olivos, «(Liquid–liquid) equilibria for ternary and quaternary systems of representative compounds of gasoline+ methanol at 293.15 K: Experimental data and correlation», Fluid Phase Equilibria, vol. 348, pp. 60-69, 2013.

P. M. Mathias, Guidelines for the Analysis of Vapor–Liquid Equilibrium Data. ACS Publications, 2017.

F. Cai et al., «Isobaric vapor–liquid equilibrium for methanol+ dimethyl carbonate+ phosphoric-based ionic liquids», Fluid Phase Equilibria, vol. 352, pp. 47-53, 2013.

M. Yakovleva, E. Vorobyov, I. Pukinsky, I. Prikhodko, G. Kuranov, y N. Smirnova, «Liquid–liquid equilibria for ternary mixtures of 2, 2-dimethyl-1, 3-dioxolane-4-methanol with n-heptane, toluene, ethanol and water», Fluid Phase Equilibria,vol. 405, pp. 107-113, 2015.

B. E. Poling, J. M. Prausnitz, y J. O. Connell, The Properties of Gases and Liquids, 5.a ed. New York: McGraw- Hill Professional, 2000.

OJS System - Metabiblioteca |